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jove.com
Video: Electrophilic Addition of HX to 1,3-Butadiene: Thermodynamic vs Kinetic Control
2.9K Views. The addition of a hydrogen halide to 1,3-butadiene gives a mixture of 1,2- and 1,4-adducts. Since more substituted alkenes are more stable, the 1,4-adduct is expected to be the major product. However, the product distribution is strongly influenced by temperature; low temperature favors the 1,2-adduct, whereas the 1,4-adduct is ...
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